Literature DB >> 29623966

Oxidation of a germanium(ii) dication to access cationic germanium(iv) fluorides.

Riccardo Suter1, Ala'aeddeen Swidan, Charles L B Macdonald, Neil Burford.   

Abstract

The synthesis and characterization of the tris(1-ethyl-benzoimidazol-2-ylmethyl)amine (BIMEt3 = L) complex of Ge(ii)2+ is described. Oxidation of [LGe]2+ with Selectfluor gives [LGeF2]2+, in a process that is envisaged to involve a tricationic complex [LGeF]3+ as an intermediate, which has been isolated by fluoride ion abstraction from [LGeF2]2+.

Entities:  

Year:  2018        PMID: 29623966     DOI: 10.1039/c8cc01799a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP]3+/[LPF2]3+ redox couple.

Authors:  Ala'aeddeen Swidan; Riccardo Suter; Charles L B Macdonald; Neil Burford
Journal:  Chem Sci       Date:  2018-06-19       Impact factor: 9.825

2.  Tweaking the Charge Transfer: Bonding Analysis of Bismuth(III) Complexes with a Flexidentate Phosphane Ligand.

Authors:  Réka Mokrai; Jamie Barrett; David C Apperley; Zoltán Benkő; Dominikus Heift
Journal:  Inorg Chem       Date:  2020-06-12       Impact factor: 5.165

  2 in total

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