Emulsions in porous media: From single droplet behavior to applications for oil recovery.

Emulsions are suspensions of droplets ubiquitous in oil recovery from underground reservoirs. Oil is typically trapped in geological porous media where emulsions are either formed in situ or injected to elicit oil mobilization and thus enhance the amount of oil recovered. Here, we briefly review basic concepts on geometrical and wetting features of porous media, including thin film stability and fluids penetration modes, which are more relevant for oil recovery and oil-contaminated aquifers. Then, we focus on the description of emulsion flow in porous media spanning from the behaviour of single droplets to the collective flow of a suspension of droplets, including the effect of bulk and interfacial rheology, hydrodynamic and physico-chemical interactions. Finally, we describe the particular case of emulsions used in underground porous media for enhanced oil recovery, thereby discussing some perspectives of future work. Although focused on oil recovery related topics, most of the insights we provide are useful towards remediation of oil-contaminated aquifers and for a basic understanding of emulsion flow in any kind of porous media, such as biological tissues.