| Literature DB >> 29575429 |
Dhika Aditya Gandamana1, Bin Wang1, Ciputra Tejo1, Benoit Bolte2, Fabien Gagosz2,3, Shunsuke Chiba1.
Abstract
A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Brønsted acid catalysis has been developed. The method is based on the use of either a benzyl or isopropyl ether as a traceless hydrogen-atom donor, and involves an intramolecular hydride transfer as a key step, which is achieved in a regio- and stereoselective manner.Entities:
Keywords: Brønsted acid; alcohols; alkenes; hydrogen-atom transfer; reduction
Year: 2018 PMID： 29575429 DOI： 10.1002/anie.201801953
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336