Literature DB >> 29575256

Towards Useful Boronates through Atom-Economical Catalyzed Cascade Reactions.

Elena Buñuel1, Diego J Cárdenas1.   

Abstract

Metal-catalyzed borylative cyclization reactions of polyunsaturated compounds allow concomitant formation of C-C and C-B bonds to provide cyclic boronates, which constitute synthetically useful intermediates. Recent developments using first-row transition metals as catalysts provide fully atom-economical reactions that follow mechanisms involving σ-bond metathesis.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  boron; cobalt; cyclization; iron; metathesis

Year:  2018        PMID： 29575256     DOI： 10.1002/chem.201800659

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  3 in total

1.  Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates.

Authors:  Natalia Cabrera-Lobera; M Teresa Quirós; William W Brennessel; Michael L Neidig; Elena Buñuel; Diego J Cárdenas
Journal:  Org Lett       Date:  2019-07-29       Impact factor: 6.005

2.  Synthesis of BN-Polyarenes by a Mild Borylative Cyclization Cascade.

Authors:  Ester Sans-Panadés; Juan J Vaquero; Manuel A Fernández-Rodríguez; Patricia García-García
Journal:  Org Lett       Date:  2022-08-01       Impact factor: 6.072

3.  Metal-Free Temperature-Controlled Regiodivergent Borylative Cyclizations of Enynes: BCl3 -Promoted Skeletal Rearrangement.

Authors:  Ana Milián; Manuel A Fernández-Rodríguez; Estíbaliz Merino; Juan J Vaquero; Patricia García-García
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-24       Impact factor: 16.823
  3 in total

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