| Literature DB >> 29573527 |
Tian-Jiao Hu1, Meng-Yao Li1, Qian Zhao2, Chen-Guo Feng1,3, Guo-Qiang Lin1.
Abstract
An efficient aryl to vinyl 1,4-palladium migration/Heck sequence was developed for the stereoselective synthesis of 1,3-dienes. High stereoselectivity was observed not only for 1,3-dienes bearing two similar aryl groups at terminal positions, but also for those with configurations shown to be unfavorable with previous methods.Entities:
Keywords: C−H functionalization; alkenylation; cross-coupling; metal migration; palladium
Year: 2018 PMID： 29573527 DOI： 10.1002/anie.201801963
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336