Literature DB >> 29560991

Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction.

Dalton B Burks1, Shakeyia Davis2, Robert W Lamb3, Xuan Liu4, Roberta R Rodrigues2, Nalaka P Liyanage2, Yujie Sun4, Charles Edwin Webster3, Jared H Delcamp2, Elizabeth T Papish1.   

Abstract

The first example of a CNC pincer ligand with a central pyridinol ligand is reported in a nickel(ii) complex. This metal complex can be protonated or deprotonated reversibly in situ to switch on or off the photocatalytic performance towards CO2 reduction. The O- substituent appears essential for catalysis.

Entities:  

Year:  2018        PMID： 29560991     DOI： 10.1039/C7CC09507D

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO2 photoreduction in a noble-metal-free system.

Authors:  Hai-Hua Huang; Ji-Hong Zhang; Miao Dai; Lianglin Liu; Zongren Ye; Jiahao Liu; Di-Chang Zhong; Jia-Wei Wang; Cunyuan Zhao; Zhuofeng Ke
Journal:  Proc Natl Acad Sci U S A       Date:  2022-08-23       Impact factor: 12.779

2.  Synthesis and Catalytic Application of Two Mononuclear Complexes Bearing Diethylenetriamine Derivative Ligand.

Authors:  Chao Liu; Zhao Yang; Hao Guo; Yu-Cai Zhao
Journal:  Molecules       Date:  2020-04-30       Impact factor: 4.411
  2 in total

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