Literature DB >> 29543001

Johari-Goldstein Relaxation Far Below T_{g}: Experimental Evidence for the Gardner Transition in Structural Glasses?

K Geirhos1, P Lunkenheimer1, A Loidl1.   

Abstract

Experimental evidence for the Gardner transition, theoretically predicted to arise deep in the glassy state of matter, is scarce. At this transition, the energy landscape sensed by the particles forming the glass is expected to become more complex. In the present Letter, we report the dielectric response of two typical glass formers with well-pronounced Johari-Goldstein β relaxation, following this response down to unprecedented low temperatures, far below the glass transition. As the Johari-Goldstein process is believed to arise from the local structure of the energy landscape, its investigation seems an ideal tool to seek evidence for the Gardner transition. Indeed, we find an unusual broadening of the β relaxation below about 110 K for sorbitol and 100 K for xylitol, in excess of the expected broadening arising from a distribution of energy barriers. These results are well consistent with the presence of the Gardner transition in canonical structural glass formers.

Entities:  

Year:  2018        PMID: 29543001     DOI: 10.1103/PhysRevLett.120.085705

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  2 in total

1.  Determining the nonequilibrium criticality of a Gardner transition via a hybrid study of molecular simulations and machine learning.

Authors:  Huaping Li; Yuliang Jin; Ying Jiang; Jeff Z Y Chen
Journal:  Proc Natl Acad Sci U S A       Date:  2021-03-16       Impact factor: 12.779

2.  Low-Frequency (Gigahertz to Terahertz) Depolarized Raman Scattering Off n-Alkanes, Cycloalkanes, and Six-Membered Rings: A Physical Interpretation.

Authors:  Andrew J Farrell; Mario González-Jiménez; Gopakumar Ramakrishnan; Klaas Wynne
Journal:  J Phys Chem B       Date:  2020-08-21       Impact factor: 2.991

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.