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Literature DB >> 29537831

Synthesis of a Gallaarsene {HC[C(Me)N-2,6- i-Pr₂-C₆H₃]₂}GaAsCp* Containing a Ga═As Double Bond.

Christoph Helling¹, Christoph Wölper¹, Stephan Schulz¹.

Abstract

Cp*AsCl2 (Cp* = C5Me5) reacts with one equivalent of LGa (L = HC[C(Me)N(2,6- i-Pr2C6H3)]2) with formation of L(Cl)GaAs(Cl)Cp* 1, whereas the reaction with two equivalents of LGa yielded gallaarsene LGaAsCp* 2 containing a Ga═As double bond and (η1-Ga(Cp*)L(η2-GaL)(μ-As3) 3. Compounds 2 and 3 were structurally characterized by single crystal X-ray diffraction, and the π-bonding contribution in 2 was analyzed by temperature-dependent 1H NMR spectroscopy (9.65 kcal mol-1) and by quantum mechanical computation.

Entities: Chemical Gene

Year: 2018 PMID： 29537831 DOI： 10.1021/jacs.8b02447

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

5 in total

1. A silicon-carbonyl complex stable at room temperature.

Authors: Chelladurai Ganesamoorthy; Juliane Schoening; Christoph Wölper; Lijuan Song; Peter R Schreiner; Stephan Schulz
Journal: Nat Chem Date: 2020-04-20 Impact factor: 24.427

2. Mechanistic insights into the insertion and addition reactions of group 13 analogues of the six-membered N-heterocyclic carbenes: interplay of electrophilicity, basicity, and aromaticity governing the reactivity.

Authors: Zheng-Feng Zhang; Ming-Der Su
Journal: RSC Adv Date: 2021-06-04 Impact factor: 4.036

Synthesis of a Gallaarsene {HC[C(Me)N-2,6- i-Pr₂-C₆H₃]₂}GaAsCp* Containing a Ga═As Double Bond.

1. A silicon-carbonyl complex stable at room temperature.

2. Mechanistic insights into the insertion and addition reactions of group 13 analogues of the six-membered N-heterocyclic carbenes: interplay of electrophilicity, basicity, and aromaticity governing the reactivity.

3. A Phosphanyl-Phosphagallene that Functions as a Frustrated Lewis Pair.

4. Synthesis and Reactivity of Heteroleptic Ga-P-C Allyl Cation Analogues.

5. Bis-Phosphaketenes LM(PCO)₂ (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.

Synthesis of a Gallaarsene {HC[C(Me)N-2,6- i-Pr2-C6H3]2}GaAsCp* Containing a Ga═As Double Bond.

1. A silicon-carbonyl complex stable at room temperature.

2. Mechanistic insights into the insertion and addition reactions of group 13 analogues of the six-membered N-heterocyclic carbenes: interplay of electrophilicity, basicity, and aromaticity governing the reactivity.

3. A Phosphanyl-Phosphagallene that Functions as a Frustrated Lewis Pair.

4. Synthesis and Reactivity of Heteroleptic Ga-P-C Allyl Cation Analogues.

5. Bis-Phosphaketenes LM(PCO)2 (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.

Synthesis of a Gallaarsene {HC[C(Me)N-2,6- i-Pr₂-C₆H₃]₂}GaAsCp* Containing a Ga═As Double Bond.

5. Bis-Phosphaketenes LM(PCO)₂ (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.