| Literature DB >> 29537276 |
Meng-Hua Wang1, You-Cai Hu2, Bing-Da Sun3, Meng Yu1, Shu-Bin Niu4, Zhe Guo1, Xiao-Yan Zhang1, Tao Zhang1, Gang Ding1, Zhong-Mei Zou1.
Abstract
The highly photosensitive characteristic of poly-sulfide chetomins was first unveiled, and four new unstable analogues, chetomins A-D (1-4), with significant cytotoxicity were successfully purified in darkness. The visible-light-induced desulfurization and intermolecular disproportionation were revealed to initiate the interconversion of chetomin analogues, which explained the long-recognized puzzle of rarity and instability of chetomin analogues.Entities:
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Year: 2018 PMID： 29537276 DOI： 10.1021/acs.orglett.8b00304
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005