| Literature DB >> 29533625 |
Airat R Tuktarov1, Arslan R Akhmetov1, Artur A Khuzin1, Usein M Dzhemilev1.
Abstract
The energy-rich methanofullerenes were synthesized for the first time by the reaction of fullerene C60 with mono- and bisquadricyclane esters of malonic acid. The C-C bond cleavage in the quadricyclane moieties of new hybrid molecules takes place in the presence of catalytic amounts of Cu, Pd, and Pt salts or complexes or SiO2 and is accompanied by heat evolution.Entities:
Year: 2018 PMID: 29533625 DOI: 10.1021/acs.joc.8b00119
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354