Literature DB >> 29517099

The n →π* interaction in metal complexes.

Jorge Echeverría1.   

Abstract

We report here, for the first time, the existence of n →π* interactions in transition metal complexes containing carbonyl ligands. This interaction has been observed to be surprisingly abundant and to stabilize precise molecular conformations that maximize the overlap between the donor and acceptor orbitals.

Entities:  

Year:  2018        PMID： 29517099     DOI： 10.1039/c8cc00763b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Synthesis and Characterization of Novel [2 + 1] Tricarbonyl Rhenium Complexes with the Hydrophilic Phosphine Ligands PTA and CAP.

Authors:  Ioanna Roupa; Charalampos Flampouraris; Antonio Shegani; Myrto Ischyropoulou; Konstantina Makrypidi; Catherine Raptopoulou; Ioannis Pirmettis; Minas S Papadopoulos; Vassilis Psycharis; Aristeidis Chiotellis
Journal:  Bioinorg Chem Appl       Date:  2022-06-13       Impact factor: 4.724

2.  Theoretical Study of the Structures of 4-(2,3,5,6-Tetrafluoropyridyl)Diphenylphosphine Oxide and Tris(Pentafluorophenyl)Phosphine Oxide: Why Does the Crystal Structure of (Tetrafluoropyridyl)Diphenylphosphine Oxide Have Two Different P=O Bond Lengths?

Authors:  Joseph R Lane; Graham C Saunders
Journal:  Molecules       Date:  2020-06-16       Impact factor: 4.411

3.  π-Hole Interactions Involving Nitro Aromatic Ligands in Protein Structures.

Authors:  Antonio Bauzá; Antonio Frontera; Tiddo Jonathan Mooibroek
Journal:  Chemistry       Date:  2019-09-17       Impact factor: 5.236

4.  n → π* interactions as a versatile tool for controlling dynamic imine chemistry in both organic and aqueous media.

Authors:  Hang Chen; Hebo Ye; Yu Hai; Ling Zhang; Lei You
Journal:  Chem Sci       Date:  2020-01-31       Impact factor: 9.825

5.  Intermolecular Non-Covalent Carbon-Bonding Interactions with Methyl Groups: A CSD, PDB and DFT Study.

Authors:  Tiddo J Mooibroek
Journal:  Molecules       Date:  2019-09-16       Impact factor: 4.411
  5 in total

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