Literature DB >> 29505052

Ruthenium-catalyzed hydrogen isotope exchange of C(sp3)-H bonds directed by a sulfur atom.

Longhui Gao1, Serge Perato1, Sébastien Garcia-Argote1, Céline Taglang1, Luis Miguel Martínez-Prieto2, Céline Chollet1, David-Alexandre Buisson1, Vincent Dauvois3, Philippe Lesot4, Bruno Chaudret2, Bernard Rousseau1, Sophie Feuillastre1, Grégory Pieters1.   

Abstract

We present here the first example of C(sp3)-H activation directed by a sulfur atom. Based on this transformation catalyzed by Ru/C, we have developed a hydrogen isotope exchange reaction for the deuterium and tritium labelling of thioether substructures in complex molecules.

Entities:  

Year:  2018        PMID： 29505052     DOI： 10.1039/c8cc00653a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Trideuteromethylation Enabled by a Sulfoxonium Metathesis Reaction.

Authors:  Zuyuan Shen; Shilei Zhang; Huihui Geng; Jiarui Wang; Xinyu Zhang; Anqi Zhou; Cheng Yao; Xiaobei Chen; Wei Wang
Journal:  Org Lett       Date:  2019-01-07       Impact factor: 6.005

2.  Direct Carbon Isotope Exchange through Decarboxylative Carboxylation.

Authors:  Cian Kingston; Michael A Wallace; Alban J Allentoff; Justine N deGruyter; Jason S Chen; Sharon X Gong; Samuel Bonacorsi; Phil S Baran
Journal:  J Am Chem Soc       Date:  2019-01-03       Impact factor: 15.419

3.  Efficient Access to Deuterated and Tritiated Nucleobase Pharmaceuticals and Oligonucleotides using Hydrogen-Isotope Exchange.

Authors:  Alberto Palazzolo; Sophie Feuillastre; Viktor Pfeifer; Sébastien Garcia-Argote; Donia Bouzouita; Simon Tricard; Céline Chollet; Elodie Marcon; David-Alexandre Buisson; Sophie Cholet; François Fenaille; Guy Lippens; Bruno Chaudret; Grégory Pieters
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-06       Impact factor: 15.336

4.  NHC-Stabilized Iridium Nanoparticles as Catalysts in Hydrogen Isotope Exchange Reactions of Anilines.

Authors:  Mégane Valero; Donia Bouzouita; Alberto Palazzolo; Jens Atzrodt; Christophe Dugave; Simon Tricard; Sophie Feuillastre; Grégory Pieters; Bruno Chaudret; Volker Derdau
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-29       Impact factor: 15.336

5.  Highly Selective Directed Iridium-Catalyzed Hydrogen Isotope Exchange Reactions of Aliphatic Amides.

Authors:  Mégane Valero; Remo Weck; Stefan Güssregen; Jens Atzrodt; Volker Derdau
Journal:  Angew Chem Int Ed Engl       Date:  2018-05-30       Impact factor: 15.336

6.  Comparison of Iridium(I) Catalysts in Temperature Mediated Hydrogen Isotope Exchange Reactions.

Authors:  Mégane Valero; Anurag Mishra; Jennifer Blass; Remo Weck; Volker Derdau
Journal:  ChemistryOpen       Date:  2019-08-01       Impact factor: 2.911

Review 7.  Trends in the Hydrogen-Deuterium Exchange at the Carbon Centers. Preparation of Internal Standards for Quantitative Analysis by LC-MS.

Authors:  Paulina Grocholska; Remigiusz Bąchor
Journal:  Molecules       Date:  2021-05-18       Impact factor: 4.411
  7 in total

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