Highly Emissive Fused Heterocyclic Alkynylgold(III) Complexes for Multiple Color Emission Spanning from Green to Red for Solution-Processable Organic Light-Emitting Devices.

A new class of fused heterocyclic tridentate ligand-containing alkynylgold(III) complexes with tunable emission color has been successfully designed and synthesized. Structural modification of the σ-donating fused heterocyclic alkynyl ligands, including substituted fluorene, carbazole, and triphenylamine, enables a large spectral shift of about 110 nm (ca. 3310 cm-1 ) that covers the green to red region to be realized with the same tridentate ligand-containing alkynylgold(III) complexes in solid-state thin films. Interestingly, the energy of the excimeric emission can be controlled by the rational design of the fused heterocyclic alkynyl ligands. Superior solution-processable organic light-emitting devices (OLEDs) with high external quantum efficiencies (EQEs) of 12.2, 13.5, 9.3, and 5.2 % were obtained with green, yellow, orange, and red emission. These high EQE values are comparable to those of the vacuum-deposited OLEDs based on structurally related alkynylgold(III) complexes.