| Literature DB >> 29493885 |
Andreas Stoy1,2, Julian Böhnke1,2, J Oscar C Jiménez-Halla3, Rian D Dewhurst1,2, Torsten Thiess1,2, Holger Braunschweig1,2.
Abstract
The room-temperature, ambient-pressure reactions of CO2 with two species containing boron-boron multiple bonds led to the incorporation of either one or two CO2 molecules. The structural characterization of a thermally unstable intermediate in one case indicates that an initial [2+2] cycloaddition is the key step in the reaction mechanism.Entities:
Keywords: CO2 fixation; boron; carbon dioxide; diborenes; diborynes
Year: 2018 PMID： 29493885 DOI： 10.1002/anie.201802117
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336