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Literature DB >> 29479606

Phosphaalkene-substituted organo-group 15 compounds: synthesis and characterisation of (NHC)P-EtBu₂ (E = P, As, Sb and Bi).

Markus Balmer¹, Hannah Gottschling, Carsten von Hänisch.

Abstract

Herein, we present the synthesis and characterisation of new group 15 element compounds with low valent phosphorus atoms as substituents. This new series of compounds includes the heavier group 15 elements and represents the rare group of compounds with a direct P-E bond (E = P, As, Sb and Bi).

Entities: Chemical Disease

Year: 2018 PMID： 29479606 DOI： 10.1039/c8cc00899j

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. Low-Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)₂ M] Exhibit P-M pπ-pπ Interaction (M=Ge, Sn, Pb).

Authors: Markus Balmer; Yannick J Franzke; Florian Weigend; Carsten von Hänisch
Journal: Chemistry Date: 2019-12-03 Impact factor: 5.236

2. Isolation of Carbene-Stabilized Arsenic Monophosphide [AsP] and its Radical Cation [AsP]^+. and Dication [AsP]².

Authors: Adinarayana Doddi; Dirk Bockfeld; Marc-Kevin Zaretzke; Thomas Bannenberg; Matthias Tamm
Journal: Chemistry Date: 2019-09-13 Impact factor: 5.236

3. Activation of the C[double bond, length as m-dash]P bond in phosphanylphosphaalkenes (C[double bond, length as m-dash]P-P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi.

Authors: Aleksandra Ziółkowska; Natalia Szynkiewicz; Łukasz Ponikiewski
Journal: RSC Adv Date: 2022-04-07 Impact factor: 3.361

Phosphaalkene-substituted organo-group 15 compounds: synthesis and characterisation of (NHC)P-EtBu₂ (E = P, As, Sb and Bi).

1. Low-Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)₂ M] Exhibit P-M pπ-pπ Interaction (M=Ge, Sn, Pb).

2. Isolation of Carbene-Stabilized Arsenic Monophosphide [AsP] and its Radical Cation [AsP]^+. and Dication [AsP]².

3. Activation of the C[double bond, length as m-dash]P bond in phosphanylphosphaalkenes (C[double bond, length as m-dash]P-P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi.

4. Metathesis Reactions of a NHC-Stabilized Phosphaborene.

Review 5. Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds.

6. Isolation of Cyclic(Alkyl)(Amino) Carbene-Bismuthinidene Mediated by a Beryllium(0) Complex.

Phosphaalkene-substituted organo-group 15 compounds: synthesis and characterisation of (NHC)P-EtBu2 (E = P, As, Sb and Bi).

1. Low-Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)2 M] Exhibit P-M pπ-pπ Interaction (M=Ge, Sn, Pb).

2. Isolation of Carbene-Stabilized Arsenic Monophosphide [AsP] and its Radical Cation [AsP]+. and Dication [AsP]2.

3. Activation of the C[double bond, length as m-dash]P bond in phosphanylphosphaalkenes (C[double bond, length as m-dash]P-P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi.

4. Metathesis Reactions of a NHC-Stabilized Phosphaborene.

Review 5. Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds.

6. Isolation of Cyclic(Alkyl)(Amino) Carbene-Bismuthinidene Mediated by a Beryllium(0) Complex.

Phosphaalkene-substituted organo-group 15 compounds: synthesis and characterisation of (NHC)P-EtBu₂ (E = P, As, Sb and Bi).

1. Low-Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)₂ M] Exhibit P-M pπ-pπ Interaction (M=Ge, Sn, Pb).

2. Isolation of Carbene-Stabilized Arsenic Monophosphide [AsP] and its Radical Cation [AsP]^+. and Dication [AsP]².