| Literature DB >> 29464254 |
Kent O Kirlikovali1, Eunho Cho, Tyler J Downard, Lilit Grigoryan, Zheng Han, Sooji Hong, Dahee Jung, Jason C Quintana, Vanessa Reynoso, Sooihk Ro, Yi Shen, Kevin Swartz, Elizabeth Ter Sahakyan, Alex I Wixtrom, Brandon Yoshida, Arnold L Rheingold, Alexander M Spokoyny.
Abstract
We report the synthesis of air-stable Pd(i) dimer complexes featuring biaryl phosphine ligands. Catalytic experiments suggest that these complexes are competent precatalysts that can mediate cross-coupling amination reactions between aryl halides with both aliphatic and aromatic amine nucleophiles. This work represents an expansion of the air-stable precatalyst toolbox for Pd-catalyzed cross-coupling transformations.Entities:
Year: 2018 PMID： 29464254 DOI： 10.1039/c8dt00119g
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390