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Literature DB >> 29446194

Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles.

Abstract

A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.

Entities: Chemical

Keywords: asymmetric catalysis; boronic acids; carbometalation; cyclopropanes; rhodium

Year: 2018 PMID： 29446194 DOI： 10.1002/anie.201713324

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

10 in total

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Journal: Chem Sci Date: 2018-07-02 Impact factor: 9.825

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Journal: Beilstein J Org Chem Date: 2019-03-21 Impact factor: 2.883

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Journal: Chem Sci Date: 2019-08-27 Impact factor: 9.825

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6. Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers.

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7. Preparation of Distant Quaternary Carbon Stereocenters by Double Selective Ring-Opening of 1,1-Biscyclopropyl Methanol Derivatives.

Authors: Yogesh Siddaraju; Juliette Sabbatani; Anthony Cohen; Ilan Marek
Journal: Angew Chem Int Ed Engl Date: 2022-05-20 Impact factor: 16.823