Literature DB >> 29445796

Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds.

Hsiu-Jung Lin1, Sean Lutz, Catherine O'Kane, Matthias Zeller, Chun-Hsing Chen, Talal Al Assil, Wei-Tsung Lee.   

Abstract

A low-coordinate iron(ii) complex (CztBu(PztBu)2)Fe[N(SiMe3)2], 1 bearing an NNN-pincer ligand was prepared and fully characterized. Intramolecular C-H activation on the 5-position of a pyrazole at elevated temperatures was observed. Complex 1 was found to be an efficient and chemoselective pre-catalyst for the hydrosilylation of organo carbonyl substrates.

Entities:  

Year:  2018        PMID： 29445796     DOI： 10.1039/c7dt04928e

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  5 in total

1.  Novel family of bis-pyrazole coordination complexes as potent antibacterial and antifungal agents.

Authors:  Youssef Draoui; Smaail Radi; Amine Tanan; Afaf Oulmidi; Haralampos N Miras; Redouane Benabbes; Sabir Ouahhoudo; Samira Mamri; Aurelian Rotaru; Yann Garcia
Journal:  RSC Adv       Date:  2022-06-15       Impact factor: 4.036

Review 2.  Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation.

Authors:  Sem Raj Tamang; Michael Findlater
Journal:  Molecules       Date:  2019-09-03       Impact factor: 4.411

3.  Trivalent Rare-Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe2 )2 by Amine-Exchange Reaction.

Authors:  Koichi Shinohara; Hayato Tsurugi; Reiner Anwander; Kazushi Mashima
Journal:  Chemistry       Date:  2020-10-01       Impact factor: 5.236

Review 4.  Applications of iron pincer complexes in hydrosilylation reactions.

Authors:  Rasheed Nihala; Kalathingal Nasreen Hisana; C M A Afsina; Gopinathan Anilkumar
Journal:  RSC Adv       Date:  2022-08-26       Impact factor: 4.036

5.  Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation.

Authors:  Yangyang Ma; Jiayun Li; Ying Bai; Jiajian Peng
Journal:  Curr Org Synth       Date:  2021       Impact factor: 2.276
  5 in total

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