Literature DB >> 29424530

Helical Rod-like Phenylene Cages via Ruthenium Catalyzed Diol-Diene Benzannulation: A Cord of Three Strands.

Hiroki Sato1, Jon A Bender1, Sean T Roberts1, Michael J Krische1.   

Abstract

p-Bromo-terminated oligo(p-phenylenevinylenes) emanating from a 1,3,5-benzene core are dihydroxylated and subjected to ruthenium catalyzed diol-diene benzannulation to form tripodal oligo(phenylenes). Copper- or nickel-mediated 3-fold reductive biaryl homocoupling delivers a series of triple-stranded phenylene cages of helical rod-like topology bearing 14, 17, and 20 benzene rings.

Entities:  

Year:  2018        PMID： 29424530     DOI： 10.1021/jacs.8b00131

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  10 in total

Review 1.  Nanographenes and Graphene Nanoribbons as Multitalents of Present and Future Materials Science.

Authors:  Yanwei Gu; Zijie Qiu; Klaus Müllen
Journal:  J Am Chem Soc       Date:  2022-06-07       Impact factor: 16.383

Review 2.  Ruthenium-Catalyzed Cycloadditions to Form Five-, Six-, and Seven-Membered Rings.

Authors:  Rosalie S Doerksen; Tomáš Hodík; Guanyu Hu; Nancy O Huynh; William G Shuler; Michael J Krische
Journal:  Chem Rev       Date:  2021-02-12       Impact factor: 60.622

3.  A hemicryptophane with a triple-stranded helical structure.

Authors:  Augustin Long; Olivier Perraud; Erwann Jeanneau; Christophe Aronica; Jean-Pierre Dutasta; Alexandre Martinez
Journal:  Beilstein J Org Chem       Date:  2018-07-24       Impact factor: 2.883

4.  Twist sense control in terminally functionalized ortho-phenylenes.

Authors:  Gopi Nath Vemuri; Rathiesh R Pandian; Brian J Spinello; Erika B Stopler; Zacharias J Kinney; C Scott Hartley
Journal:  Chem Sci       Date:  2018-09-05       Impact factor: 9.825

5.  Alternating oligo(o,p-phenylenes) via ruthenium catalyzed diol-diene benzannulation: orthogonality to cross-coupling enables de novo nanographene and PAH construction.

Authors:  Zachary A Kasun; Hiroki Sato; Jing Nie; Yasuyuki Mori; Jon A Bender; Sean T Roberts; Michael J Krische
Journal:  Chem Sci       Date:  2018-08-30       Impact factor: 9.825

6.  Transformation of Imine Cages into Hydrocarbon Cages.

Authors:  Tobias H G Schick; Jochen C Lauer; Frank Rominger; Michael Mastalerz
Journal:  Angew Chem Int Ed Engl       Date:  2019-01-15       Impact factor: 15.336

7.  Macrocycles of higher ortho-phenylenes: assembly and folding.

Authors:  Zacharias J Kinney; Viraj C Kirinda; C Scott Hartley
Journal:  Chem Sci       Date:  2019-08-09       Impact factor: 9.825

8.  A minimal cage of a diamond twin with chirality.

Authors:  Toshiya M Fukunaga; Takahide Kato; Koki Ikemoto; Hiroyuki Isobe
Journal:  Proc Natl Acad Sci U S A       Date:  2022-02-15       Impact factor: 12.779

9.  Rationalization of chirality transfer and fast conformational changes in a tris(2-pyridylmethyl)amine-based cage.

Authors:  Gege Qiu; Djamel Eddine Khatmi; Alexandre Martinez; Paola Nava
Journal:  RSC Adv       Date:  2021-04-13       Impact factor: 3.361

10.  Chiral cyclic [n]spirobifluorenylenes: carbon nanorings consisting of helically arranged quaterphenyl rods illustrating partial units of woven patterns.

Authors:  Kaige Zhu; Kosuke Kamochi; Takuya Kodama; Mamoru Tobisu; Toru Amaya
Journal:  Chem Sci       Date:  2020-08-15       Impact factor: 9.825
  10 in total

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