Literature DB >> 29417101

Ionic liquids in cross-coupling reactions: "liquid" solutions to a "solid" precipitation problem.

Hemant Choudhary1, Paula Berton, Gabriela Gurau, Allan S Myerson, Robin D Rogers.   

Abstract

To alleviate the problem of solid salt precipitation when using inorganic bases in cross-coupling reactions, basic anions were combined with the trihexyl(tetradecyl)phosphonium ([P66614]+) cation to ensure an ionic liquid byproduct. If the starting base is also an ionic liquid, as is the case for [P66614][OH]·4MeOH, it can be used as both base and solvent.

Entities:  

Year:  2018        PMID： 29417101     DOI： 10.1039/c7cc09635f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  New Trends in C-C Cross-Coupling Reactions: The Use of Unconventional Conditions.

Authors:  Marta A Andrade; Luísa M D R S Martins
Journal:  Molecules       Date:  2020-11-24       Impact factor: 4.411

2.  Biological and catalytic potential of sustainable low and high valent metal-Schiff base sulfonate salicylidene pincer complexes.

Authors:  Mohamed Shaker S Adam; Omar M El-Hady; Farman Ullah
Journal:  RSC Adv       Date:  2019-10-25       Impact factor: 4.036

3.  Renewable Schiff-Base Ionic Liquids for Lignocellulosic Biomass Pretreatment.

Authors:  Hemant Choudhary; Venkataramana R Pidatala; Mood Mohan; Blake A Simmons; John M Gladden; Seema Singh
Journal:  Molecules       Date:  2022-09-23       Impact factor: 4.927
  3 in total

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