Literature DB >> 29411832

[Yb(AAZTA)(H2O)]-: an unconventional ParaCEST MRI probe.

Daniela Delli Castelli1, Lorenzo Tei, Fabio Carniato, Silvio Aime, Mauro Botta.   

Abstract

An unexpectedly slow exchange rate has been observed for the coordinated water molecule of [Yb(AAZTA)(H2O)]- using 1H-NMR and CEST-MRI studies. This made it possible for the first time to exploit the bound water molecule of a LnIII complex with carboxylic donor groups for CEST imaging. This result envisages the development of a new family of thermodynamically stable ParaCEST probes based on anionic chelates.

Entities:  

Year:  2018        PMID: 29411832     DOI: 10.1039/c8cc00193f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Surprising Complexity of the [Gd(AAZTA)(H2O)2]- Chelate Revealed by NMR in the Frequency and Time Domains.

Authors:  Daniela Lalli; Fabio Carniato; Lorenzo Tei; Carlos Platas-Iglesias; Mauro Botta
Journal:  Inorg Chem       Date:  2021-12-10       Impact factor: 5.165

  1 in total

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