First row transition metal complexes (Ni, Co, Cu, Zn) with N,N-disubstituted-N'-acylthiourea ligands have been synthesized and characterized. Bis(N,N-diisopropyl-N'-cinnamoylthiourea)nickel was found to have the lowest onset temperature for thermal decomposition. Thin film deposition of Ni, Co, and Zn sulfides by aerosol assisted chemical vapor deposition from their respective N,N-diisopropyl-N'-cinnamoylthiourea complexes at 350 °C has been demonstrated.
First row transition n class="Chemical">metalcomplexes (Ni, Co, Cu, Zn) with N,N-disubstituted-N'-acylthiourea ligands have been synthesized and characterized. Bis(N,N-diisopropyl-N'-cinnamoylthiourea)nickel was found to have the lowest onset temperature for thermal decomposition. Thin film deposition of Ni, Co, and Zn sulfides by aerosol assisted chemical vapor deposition from their respective N,N-diisopropyl-N'-cinnamoylthioureacomplexes at 350 °C has been demonstrated.
Authors: Yong Sun Won; Young Seok Kim; Timothy J Anderson; Laurel L Reitfort; Ion Ghiviriga; Lisa McElwee-White Journal: J Am Chem Soc Date: 2006-10-25 Impact factor: 15.419
Authors: Sixberth Mlowe; David J Lewis; Mohammad Azad Malik; James Raftery; Egid B Mubofu; Paul O'Brien; Neerish Revaprasadu Journal: Dalton Trans Date: 2016-01-06 Impact factor: 4.390