| Literature DB >> 29404555 |
P M May1, D Batka, G Hefter, E Königsberger, D Rowland.
Abstract
New Raman spectra of Na2S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S2-(aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S2-(aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.Entities:
Year: 2018 PMID: 29404555 DOI: 10.1039/c8cc00187a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222