| Literature DB >> 29364654 |
Jorge Albalad1, Heng Xu1, Felipe Gándara2, Mohamed Haouas3, Charlotte Martineau-Corcos3,4, Rubén Mas-Ballesté5, Sarah A Barnett6, Judith Juanhuix7, Inhar Imaz1, Daniel Maspoch1,8.
Abstract
We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.Entities:
Year: 2018 PMID: 29364654 DOI: 10.1021/jacs.7b12913
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419