| Literature DB >> 29356196 |
Christopher Frazee1, Neil Burford1, Robert McDonald2, Michael J Ferguson2, Andreas Decken3, Brian O Patrick4.
Abstract
Reaction of Ph2 SbCl3 with 2,2'-bipyridine and Me3 SiOSO2 CF3 releases chlorobenzene, which is interpreted as a reductive (SbV /SbIII ) elimination from a complex of a stiboranium cation. Conversely, reactions of Ph2 SbCl3 with 4-methylpyridine-N-oxide and AgOSO2 CF3 give redox-resistant complexes with the generic formulae [Ph2 SbCl3-x Lx+1 ][OTf]x , including a compound containing a pnictogen(V) trication.Entities:
Keywords: antimony; cations; redox reactions; trications
Year: 2018 PMID： 29356196 DOI： 10.1002/chem.201800196
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236