| Literature DB >> 29327935 |
Hua Zhou1, Paramita Mukherjee2, Rongqiang Liu1, Edelweiss Evrard3, Dianpeng Wang1, John M Humphrey2, Todd W Butler2, Lise R Hoth2, Jeffrey B Sperry2, Sylvie K Sakata4, Christopher J Helal2, Christopher W Am Ende2.
Abstract
The design, synthesis, and application of [4-(acetylamino)phenyl]imidodisulfuryl difluoride (AISF), a shelf-stable, crystalline reagent for the synthesis of sulfur(VI) fluorides, is described. The utility of AISF is demonstrated in the synthesis of a diverse array of aryl fluorosulfates and sulfamoyl fluorides under mild conditions. Additionally, a single-step preparation of AISF was developed that installed the bis(fluorosulfonyl)imide group on acetanilide utilizing an oxidative C-H functionalization protocol.Entities:
Year: 2018 PMID： 29327935 DOI： 10.1021/acs.orglett.7b03950
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005