Literature DB >> 29327755

Reversible three equal-step spin crossover in an iron(ii) Hofmann-type metal-organic framework.

Fu-Ling Liu1, Dong Li, Li-Jie Su, Jun Tao.   

Abstract

A novel bent ligand-pillared three-dimensional Hofmann-type metal-organic framework, [FeII(Hbpt)Pt(CN)4]·1/2Hbpt·1/2CH3OH·5/2H2O [1, Hbpt = 4,4'-(1H-1,2,4-triazole-3,5-diyl) dipyridine], was synthesized and crystallographically and magnetically characterized, which showed incomplete three-step spin-crossover behavior with a reversible three equal-step sequence of HS1.00 ↔ HS0.75LS0.25 ↔ HS0.5LS0.5 ↔ HS0.25LS0.75.

Entities:  

Year:  2018        PMID: 29327755     DOI: 10.1039/c7dt04205a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Di- and Tri-nuclear VIII and CrIII Complexes of Dipyridyltriazoles: Ligand Rearrangements, Mixed Valency and Ferromagnetic Coupling.

Authors:  Julia Rinck; Jonathan A Kitchen; Anthony B Carter; Yanhua Lan; Christopher E Anson; Karin Fink; Sally Brooker; Annie K Powell
Journal:  Front Chem       Date:  2020-07-09       Impact factor: 5.221

  1 in total

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