Literature DB >> 29316187

Electrochemical C-H/N-H Activation by Water-Tolerant Cobalt Catalysis at Room Temperature.

Cong Tian1, Leonardo Massignan1, Tjark H Meyer1, Lutz Ackermann1.   

Abstract

Electrochemistry enabled C-H/N-H functionalizations at room temperature by external oxidant-free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold proceeds with excellent levels of chemoselectivity and positional selectivity, and with ample scope, thus allowing electrochemical C-H activation under exceedingly mild reaction conditions at room temperature in water.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−H activation; alkynes; cobalt; electrochemistry; synthetic methods

Year:  2018        PMID： 29316187     DOI： 10.1002/anie.201712647

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  16 in total

1.  Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles.

Authors:  Chen-Yan Cai; Hai-Chao Xu
Journal:  Nat Commun       Date:  2018-09-03       Impact factor: 14.919

2.  Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations.

Authors:  Long Yang; Ralf Steinbock; Alexej Scheremetjew; Rositha Kuniyil; Lars H Finger; Antonis M Messinis; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-05-12       Impact factor: 15.336

3.  Cobalta-Electrocatalyzed C-H Activation in Biomass-Derived Glycerol: Powered by Renewable Wind and Solar Energy.

Authors:  Tjark H Meyer; Gleb A Chesnokov; Lutz Ackermann
Journal:  ChemSusChem       Date:  2020-01-30       Impact factor: 8.928

Review 4.  Synthetic Organic "Aquachemistry" that Relies on Neither Cosolvents nor Surfactants.

Authors:  Taku Kitanosono; Shu Kobayashi
Journal:  ACS Cent Sci       Date:  2021-04-21       Impact factor: 14.553

5.  Carboxylate breaks the arene C-H bond via a hydrogen-atom-transfer mechanism in electrochemical cobalt catalysis.

Authors:  Xin-Ran Chen; Shuo-Qing Zhang; Tjark H Meyer; Chun-Hui Yang; Qin-Hao Zhang; Ji-Ren Liu; Hua-Jian Xu; Fa-He Cao; Lutz Ackermann; Xin Hong
Journal:  Chem Sci       Date:  2020-05-19       Impact factor: 9.825

6.  Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne.

Authors:  Shan Tang; Dan Wang; Yichang Liu; Li Zeng; Aiwen Lei
Journal:  Nat Commun       Date:  2018-02-23       Impact factor: 14.919

7.  Insights into Cobalta(III/IV/II)-Electrocatalysis: Oxidation-Induced Reductive Elimination for Twofold C-H Activation.

Authors:  Tjark H Meyer; João C A Oliveira; Debasish Ghorai; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-05-05       Impact factor: 15.336

8.  Thiocarbonyl-enabled ferrocene C-H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical.

Authors:  Santhivardhana Reddy Yetra; Zhigao Shen; Hui Wang; Lutz Ackermann
Journal:  Beilstein J Org Chem       Date:  2018-06-25       Impact factor: 2.883

9.  Facile Electrochemical Intramolecular Amination of Urea-Tethered Terminal Alkenes for the Synthesis of Cyclic Ureas.

Authors:  Nisar Ahmed; Saira Khatoon
Journal:  ChemistryOpen       Date:  2018-07-09       Impact factor: 2.911

10.  Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources.

Authors:  Haibo Mei; Jiang Liu; Yunjie Guo; Jianlin Han
Journal:  ACS Omega       Date:  2019-08-20
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