Literature DB >> 29303517

Palladium-catalyzed enantioselective C(sp2)-H arylation of ferrocenyl ketones enabled by a chiral transient directing group.

Jiancong Xu1, Yang Liu, Jinling Zhang, Xiaohua Xu, Zhong Jin.   

Abstract

Palladium-catalyzed enantioselective C(sp2)-H activation of ferrocenyl ketones is achieved through utilizing catalytic, inexpensive l-tert-leucine as a chiral transient directing group. The transformation allows rapid access to ferrocene scaffolds simultaneously possessing planar- and stereogenic central chirality, widely applied in the ferrocene-based chiral ligand families.

Entities:  

Year:  2018        PMID： 29303517     DOI： 10.1039/c7cc09273c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Transient directing group enabled Pd-catalyzed C-H oxygenation of benzaldehydes and benzylic amines.

Authors:  Mixiang Tian; Lidong Shao; Xiaosan Su; Xuhong Zhou; Honglei Zhang; Kun Wei; Ruifen Sun; Junliang Wang
Journal:  RSC Adv       Date:  2022-06-27       Impact factor: 4.036

2.  PdII -Catalyzed Enantioselective C(sp3 )-H Arylation of Cyclobutyl Ketones Using a Chiral Transient Directing Group.

Authors:  Li-Jun Xiao; Kai Hong; Fan Luo; Liang Hu; William R Ewing; Kap-Sun Yeung; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2020-04-01       Impact factor: 15.336

3.  Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes.

Authors:  Zhong-Jian Cai; Chen-Xu Liu; Qiang Wang; Qing Gu; Shu-Li You
Journal:  Nat Commun       Date:  2019-09-13       Impact factor: 14.919

4.  PdII -Catalyzed C(alkenyl)-H Activation Facilitated by a Transient Directing Group.

Authors:  Mingyu Liu; Juntao Sun; Tuğçe G Erbay; Hui-Qi Ni; Raúl Martín-Montero; Peng Liu; Keary M Engle
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-26       Impact factor: 16.823

5.  Naphthalene Exchange in [Re(η6 -napht)2 ]+ with Pharmaceuticals Leads to Highly Functionalized Sandwich Complexes [M(η6 -pharm)2 ]+ (M=Re/99m Tc).

Authors:  Qaisar Nadeem; Federica Battistin; Olivier Blacque; Roger Alberto
Journal:  Chemistry       Date:  2021-12-13       Impact factor: 5.020

6.  Thiocarbonyl-enabled ferrocene C-H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical.

Authors:  Santhivardhana Reddy Yetra; Zhigao Shen; Hui Wang; Lutz Ackermann
Journal:  Beilstein J Org Chem       Date:  2018-06-25       Impact factor: 2.883

7.  Catalytic Asymmetric C-H Arylation of (η6-Arene)Chromium Complexes: Facile Access to Planar-Chiral Phosphines.

Authors:  María Batuecas; Junfei Luo; Ivana Gergelitsová; Katrina Krämer; Daniel Whitaker; Iñigo J Vitorica-Yrezabal; Igor Larrosa
Journal:  ACS Catal       Date:  2019-04-25       Impact factor: 13.084
  7 in total

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