Literature DB >> 29303264

Directed Decarbonylation of Unstrained Aryl Ketones via Nickel-Catalyzed C-C Bond Cleavage.

Tian-Tian Zhao1, Wen-Hua Xu1, Zhao-Jing Zheng2, Peng-Fei Xu2, Hao Wei1.   

Abstract

The nickel-catalyzed decarbonylation of unstrained diaryl ketones has been developed. The reaction is catalyzed by a combination of Ni(cod)2 and an electron-rich N-heterocyclic carbene ligand. High functional group tolerance and excellent yields (up to 98%) are observed. This strategy provides an alternative and versatile approach to construct biaryls using an inexpensive nickel catalyst.

Entities:  

Year:  2018        PMID： 29303264     DOI： 10.1021/jacs.7b11591

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  Nickel-catalyzed skeletal transformation of tropone derivatives via C-C bond activation: catalyst-controlled access to diverse ring systems.

Authors:  Takuya Kodama; Kanako Saito; Mamoru Tobisu
Journal:  Chem Sci       Date:  2022-04-04       Impact factor: 9.969

2.  Decarbonylative Suzuki-Miyaura Cross-Coupling of Aroyl Chlorides.

Authors:  Tongliang Zhou; Pei-Pei Xie; Chong-Lei Ji; Xin Hong; Michal Szostak
Journal:  Org Lett       Date:  2020-08-10       Impact factor: 6.005

3.  Ruthenium-Catalyzed Reductive Cleavage of Unstrained Aryl-Aryl Bonds: Reaction Development and Mechanistic Study.

Authors:  Jun Zhu; Peng-Hao Chen; Gang Lu; Peng Liu; Guangbin Dong
Journal:  J Am Chem Soc       Date:  2019-11-12       Impact factor: 15.419

4.  Nickel-catalyzed decarbonylation of N-acylated N-heteroarenes.

Authors:  Toshifumi Morioka; Syun Nakatani; Yuki Sakamoto; Takuya Kodama; Sensuke Ogoshi; Naoto Chatani; Mamoru Tobisu
Journal:  Chem Sci       Date:  2019-05-29       Impact factor: 9.825

5.  Light-driven transition-metal-free direct decarbonylation of unstrained diaryl ketones via a dual C-C bond cleavage.

Authors:  Dawei Cao; Mohamad Ataya; Zhangpei Chen; Huiying Zeng; Yong Peng; Rustam Z Khaliullin; Chao-Jun Li
Journal:  Nat Commun       Date:  2022-04-04       Impact factor: 14.919

6.  Cobalt-catalyzed intramolecular decarbonylative coupling of acylindoles and diarylketones through the cleavage of C-C bonds.

Authors:  Tian-Yang Yu; Wen-Hua Xu; Hong Lu; Hao Wei
Journal:  Chem Sci       Date:  2020-10-16       Impact factor: 9.825

7.  Decarbonylative Sonogashira Cross-Coupling of Carboxylic Acids.

Authors:  Chengwei Liu; Michal Szostak
Journal:  Org Lett       Date:  2021-06-07       Impact factor: 6.072
  7 in total

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