Literature DB >> 29285845

A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes.

Lucie Norel1,2, Lucy E Darago1, Boris Le Guennic2, Khetpakorn Chakarawet1, Miguel I Gonzalez1, Jacob H Olshansky1, Stéphane Rigaut2, Jeffrey R Long1.   

Abstract

The first dysprosium complexes with a terminal fluoride ligand are obtained as air-stable compounds. The strong, highly electrostatic dysprosium-fluoride bond generates a large axial crystal-field splitting of the J=15/2 ground state, as evidenced by high-resolution luminescence spectroscopy and correlated with the single-molecule magnet behavior through experimental magnetic susceptibility data and ab initio calculations.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  ab initio calculations; dysprosium; luminescence; magnetic properties; structure determination

Year:  2018        PMID： 29285845     DOI： 10.1002/anie.201712139

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  Solvent-tuned magnetic exchange interactions in Dy2 systems ligated by a μ-phenolato heptadentate Schiff base.

Authors:  Zhijie Jiang; Lin Sun; Min Li; Haipeng Wu; Zhengqiang Xia; Hongshan Ke; Yiquan Zhang; Gang Xie; Sanping Chen
Journal:  RSC Adv       Date:  2019-12-02       Impact factor: 4.036

2.  Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet.

Authors:  Mikkel A Sørensen; Ursula B Hansen; Mauro Perfetti; Kasper S Pedersen; Elena Bartolomé; Giovanna G Simeoni; Hannu Mutka; Stéphane Rols; Minki Jeong; Ivica Zivkovic; Maria Retuerto; Ana Arauzo; Juan Bartolomé; Stergios Piligkos; Høgni Weihe; Linda H Doerrer; Joris van Slageren; Henrik M Rønnow; Kim Lefmann; Jesper Bendix
Journal:  Nat Commun       Date:  2018-03-29       Impact factor: 14.919

3.  Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single-Ion Magnets.

Authors:  Angelos B Canaj; Sourav Dey; Emma Regincós Martí; Claire Wilson; Gopalan Rajaraman; Mark Murrie
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-22       Impact factor: 15.336

4.  Sorting Phenomena and Chirality Transfer in Fluoride-Bridged Macrocyclic Rare Earth Complexes.

Authors:  Katarzyna Ślepokura; Trevor A Cabreros; Gilles Muller; Jerzy Lisowski
Journal:  Inorg Chem       Date:  2021-11-16       Impact factor: 5.165

5.  In situ tracking and characterisation of scorpionate ligands via 11B-NMR spectroscopy.

Authors:  Jarrod R Thomas; Scott A Sulway
Journal:  RSC Adv       Date:  2021-04-30       Impact factor: 4.036

6.  Dinuclear Fluoride Single-Bridged Lanthanoid Complexes as Molecule Magnets: Unprecedented Coupling Constant in a Fluoride-Bridged Gadolinium Compound.

Authors:  Julio Corredoira-Vázquez; Cristina González-Barreira; Matilde Fondo; Ana M García-Deibe; Jesús Sanmartín-Matalobos; Silvia Gómez-Coca; Eliseo Ruiz; Enrique Colacio
Journal:  Inorg Chem       Date:  2022-06-23       Impact factor: 5.436

7.  Importance of an Axial LnIII-F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues.

Authors:  Emma Regincós Martí; Angelos B Canaj; Tanu Sharma; Anna Celmina; Claire Wilson; Gopalan Rajaraman; Mark Murrie
Journal:  Inorg Chem       Date:  2022-06-21       Impact factor: 5.436
  7 in total

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