Literature DB >> 29271003

Evaluation of a P,N-ligated iridium(I) catalyst in hydrogen isotope exchange reactions of aryl and heteroaryl compounds.

Mégane Valero1, Annina Burhop1, Kristof Jess2, Remo Weck1, Matthias Tamm2, Jens Atzrodt1, Volker Derdau1.   

Abstract

We have developed a novel and efficient iridium-catalyzed hydrogen isotope exchange reaction method with secondary and tertiary sulfonamides at ambient temperatures. Furthermore N-oxides and phosphonamides have been successfully applied in hydrogen isotope exchange reactions with moderate to excellent deuterium introduction.
Copyright © 2017 John Wiley & Sons, Ltd.

Entities:  

Keywords:  catalysis; deuterium; hydrogen isotope exchange; iridium

Mesh:

Substances:

Year:  2018        PMID: 29271003     DOI: 10.1002/jlcr.3595

Source DB:  PubMed          Journal:  J Labelled Comp Radiopharm        ISSN: 0362-4803            Impact factor:   1.921


  4 in total

1.  Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications.

Authors:  Rebeca Arevalo; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2019-05-28       Impact factor: 15.419

2.  NHC-Stabilized Iridium Nanoparticles as Catalysts in Hydrogen Isotope Exchange Reactions of Anilines.

Authors:  Mégane Valero; Donia Bouzouita; Alberto Palazzolo; Jens Atzrodt; Christophe Dugave; Simon Tricard; Sophie Feuillastre; Grégory Pieters; Bruno Chaudret; Volker Derdau
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-29       Impact factor: 15.336

3.  Highly Selective Directed Iridium-Catalyzed Hydrogen Isotope Exchange Reactions of Aliphatic Amides.

Authors:  Mégane Valero; Remo Weck; Stefan Güssregen; Jens Atzrodt; Volker Derdau
Journal:  Angew Chem Int Ed Engl       Date:  2018-05-30       Impact factor: 15.336

4.  Comparison of Iridium(I) Catalysts in Temperature Mediated Hydrogen Isotope Exchange Reactions.

Authors:  Mégane Valero; Anurag Mishra; Jennifer Blass; Remo Weck; Volker Derdau
Journal:  ChemistryOpen       Date:  2019-08-01       Impact factor: 2.911

  4 in total

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