| Literature DB >> 29266609 |
Heidi L van de Wouw1, Jae Young Lee1, Elorm C Awuyah1, Rebekka S Klausen1.
Abstract
BN 2-vinylnaphthalene, a BN aromatic vinyl monomer, is copolymerized with styrene under free radical conditions. Oxidation yields styrene-vinyl alcohol (SVA) statistical copolymers with tunable hydroxy group content. Comprehensive spectroscopic investigation provides proof of structure. Physical properties that vary systematically with hydroxy content include solubility and glass transition temperature. BN aromatic polymers represent a platform for the preparation of diverse functional polymeric architectures via the remarkable reaction chemistry of C-B bonds.Entities:
Keywords: amphiphiles; boranes; copolymerization; heterocycles; oxidation
Year: 2018 PMID： 29266609 DOI： 10.1002/anie.201711650
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336