Literature DB >> 29260809

Thiomolybdate [Mo3S13]2- nanocluster: a molecular mimic of MoS2 active sites for highly efficient photocatalytic hydrogen evolution.

Yonggang Lei1, Meiqun Yang, Jianhua Hou, Fang Wang, Entian Cui, Chao Kong, Shixiong Min.   

Abstract

Thiomolybdate [Mo3S13]2- nanoclusters, as a molecular mimic of MoS2 edge sites, showed high efficiency in catalyzing photochemical H2 evolution from a molecular system of Ru(bpy)3Cl2-ascorbic acid (H2A) under visible light irradiation (≥420 nm), providing a turnover number of 1570 and an initial turnover frequency of 335 h-1 for H2 evolution based on the [Mo3S13]2- catalyst.

Entities:  

Year:  2018        PMID: 29260809     DOI: 10.1039/c7cc08178b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Surface Anchoring and Active Sites of [Mo3S13]2- Clusters as Co-Catalysts for Photocatalytic Hydrogen Evolution.

Authors:  Samar Batool; Sreejith P Nandan; Stephen Nagaraju Myakala; Ashwene Rajagopal; Jasmin S Schubert; Pablo Ayala; Shaghayegh Naghdi; Hikaru Saito; Johannes Bernardi; Carsten Streb; Alexey Cherevan; Dominik Eder
Journal:  ACS Catal       Date:  2022-05-20       Impact factor: 13.700

2.  Polyampholytic Graft Copolymers as Matrix for TiO2 /Eosin Y/[Mo3 S13 ]2- Hybrid Materials and Light-Driven Catalysis.

Authors:  Afshin Nabiyan; Johannes Bernhard Max; Christof Neumann; Magdalena Heiland; Andrey Turchanin; Carsten Streb; Felix Helmut Schacher
Journal:  Chemistry       Date:  2021-03-08       Impact factor: 5.020

3.  Structural Properties of Gas Phase Molybdenum Sulfide Clusters [Mo3S13]2-, [HMo3S13]-, and [H3Mo3S13]+ as Model Systems of a Promising Hydrogen Evolution Catalyst.

Authors:  Aristeidis Baloglou; Milan Ončák; Marie-Luise Grutza; Christian van der Linde; Philipp Kurz; Martin K Beyer
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2018-10-16       Impact factor: 4.126

  3 in total

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