Electrostatic Self-Assembly: Understanding the Significance of the Solvent.

The electrostatic deposition of particles has become a very effective route to the assembly of many nanoscale materials. However, fundamental limitations to the process are presented by the choice of solvent, which can either suppress or promote self-assembly depending on specific combinations of nanoparticle/surface/solvent properties. A new development in the theory of electrostatic interactions between polarizable objects provides insight into the effect a solvent can have on electrostatic self-assembly. Critical to assembly is the requirement for a minimum charge on a surface of an object, below which a solvent can suppress electrostatic attraction. Examples drawn from the literature are used to illustrate how switches in behavior are mediated by the solvent; these in turn provide a fundamental understanding of electrostatic particle-surface interactions applicable to many areas of materials science and nanotechnology.