Literature DB >> 29235723

Cyclopentanone Derivatives from 5-Hydroxymethylfurfural via 1-Hydroxyhexane-2,5-dione as Intermediate.

Bartosz Wozniak1, Anke Spannenberg1, Yuehui Li2, Sandra Hinze1, Johannes G de Vries1.   

Abstract

An efficient strategy for the conversion of biomass derived 5-hydroxymethylfurfural (HMF) into 2-hydroxy-3-methylcyclopent-2-enone (MCP) by an intramolecular aldol condensation of 1-hydroxyhexane-2,5-dione (HHD) has been developed. Further transformations of MCP towards the diol, enol acetate, levulinic acid and N-heterocyclic compounds are also reported.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  biomass; cycloketones; homogeneous catalysis; platform chemicals; renewable resources

Mesh：

Substances：

Year:  2017        PMID： 29235723     DOI： 10.1002/cssc.201702100

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  5 in total

1.  Preparation of 1-Hydroxy-2,5-hexanedione from HMF by the Combination of Commercial Pd/C and Acetic Acid.

Authors:  Yanliang Yang; Dexi Yang; Chi Zhang; Min Zheng; Ying Duan
Journal:  Molecules       Date:  2020-05-27       Impact factor: 4.411

2.  Tungsten Promoted Ni/Al2O3 as a Noble-Metal-Free Catalyst for the Conversion of 5-Hydroxymethylfurfural to 1-Hydroxy-2,5-Hexanedione.

Authors:  Ying Duan; Rui Wang; Qihang Liu; Xuya Qin; Zuhuan Li
Journal:  Front Chem       Date:  2022-03-09       Impact factor: 5.221

3.  Tuning the Selectivity of the Hydrogenation/Hydrogenolysis of 5-Hydroxymethylfurfural under Batch Multiphase and Continuous-Flow Conditions.

Authors:  Daily Rodríguez-Padrón; Alvise Perosa; Lilia Longo; Rafael Luque; Maurizio Selva
Journal:  ChemSusChem       Date:  2022-06-28       Impact factor: 9.140

Review 4.  Advances in Catalytic Routes for the Homogeneous Green Conversion of the Bio-Based Platform 5-Hydroxymethylfurfural.

Authors:  Alessandro Messori; Andrea Fasolini; Rita Mazzoni
Journal:  ChemSusChem       Date:  2022-05-12       Impact factor: 9.140

Review 5.  The Increasing Value of Biomass: Moving From C6 Carbohydrates to Multifunctionalized Building Blocks via 5-(hydroxymethyl)furfural.

Authors:  Konstantin I Galkin; Valentine P Ananikov
Journal:  ChemistryOpen       Date:  2020-11-06       Impact factor: 2.630
  5 in total

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