| Literature DB >> 29226932 |
Michael Lesslie1, Yang Yang, Allan J Canty, Elettra Piacentino, Francis Berthias, Philippe Maitre, Victor Ryzhov, Richard A J O'Hair.
Abstract
A new decarbonylation reaction is observed for [(K2-acetate)Pd(K2-diphosphine)]+ complexes. Gas-phase IR experiments identify the product as [CH3Pd(OP(Ph2)CH2PPh2)]+. DFT calculations uncovered a plausible mechanism involving O atom abstraction by the diphosphine ligand within the coordination sphere to yield the acetyl complex, [CH3COPd(OP(Ph2)CH2PPh2)]+, which then undergoes decarbonylation.Entities:
Year: 2018 PMID： 29226932 DOI： 10.1039/c7cc08944a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222