| Literature DB >> 29219322 |
Venu Srinivas1, Yumiko Nakajima1, Kazuhiko Sato1, Shigeru Shimada1.
Abstract
Hydrosilylation of various sulfur-containing olefins with (RO)3SiH has been achieved using iridium catalysts [IrX(cod)]2 (X = Cl, SPh). The catalysis is applicable to the chemoselective hydrosilylation of thioacetate, which enables the preparation of an industrially important silane coupling agent.Entities:
Year: 2017 PMID： 29219322 DOI： 10.1021/acs.orglett.7b02940
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005