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Literature DB >> 29219236

A Step Closer to Metal-Free Dinitrogen Activation: A New Chapter in the Chemistry of Frustrated Lewis Pairs.

Abstract

The end of the metal age: Recent developments in small-molecule activation and chemical transformations of main-group species pose the question as to whether metal catalysts could be avoided altogether in the activation of dinitrogen. A ground-breaking study by Stephan and co-workers clearly implies that the metal-free activation of N2 with frustrated Lewis pairs may be achievable in the not-too-distant future.

Entities: Chemical

Keywords: dinitrogen; diphenyldiazomethane; frustrated Lewis pairs; hydroboration; tris(pentafluorophenyl)borane

Year: 2017 PMID： 29219236 DOI： 10.1002/anie.201711945

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

6 in total

1. Ta₂ ⁺-mediated ammonia synthesis from N₂ and H₂ at ambient temperature.

Authors: Caiyun Geng; Jilai Li; Thomas Weiske; Helmut Schwarz
Journal: Proc Natl Acad Sci U S A Date: 2018-10-23 Impact factor: 11.205

2. B(C₆F₅)₃-catalyzed dehydrogenative cyclization of N-tosylhydrazones and anilines via a Lewis adduct: a combined experimental and computational investigation.

Authors: Murali Mohan Guru; Sriman De; Sayan Dutta; Debasis Koley; Biplab Maji
Journal: Chem Sci Date: 2019-07-05 Impact factor: 9.825

6. Understanding the Influence of Donor-Acceptor Diazo Compounds on the Catalyst Efficiency of B(C₆ F₅ )₃ Towards Carbene Formation.

Authors: Rasool Babaahmadi; Ayan Dasgupta; Christopher J T Hyland; Brian F Yates; Rebecca L Melen; Alireza Ariafard
Journal: Chemistry Date: 2022-01-27 Impact factor: 5.020

6 in total

A Step Closer to Metal-Free Dinitrogen Activation: A New Chapter in the Chemistry of Frustrated Lewis Pairs.

1. Ta₂ ⁺-mediated ammonia synthesis from N₂ and H₂ at ambient temperature.

2. B(C₆F₅)₃-catalyzed dehydrogenative cyclization of N-tosylhydrazones and anilines via a Lewis adduct: a combined experimental and computational investigation.

3. Reactions of Frustrated Lewis Pairs with Chloro-Diazirines: Cleavage of N=N Double Bonds.

Review 4. Boron: Its Role in Energy-Related Processes and Applications.

5. Triarylborane-Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds.

6. Understanding the Influence of Donor-Acceptor Diazo Compounds on the Catalyst Efficiency of B(C₆ F₅ )₃ Towards Carbene Formation.

A Step Closer to Metal-Free Dinitrogen Activation: A New Chapter in the Chemistry of Frustrated Lewis Pairs.

1. Ta2 +-mediated ammonia synthesis from N2 and H2 at ambient temperature.

2. B(C6F5)3-catalyzed dehydrogenative cyclization of N-tosylhydrazones and anilines via a Lewis adduct: a combined experimental and computational investigation.

3. Reactions of Frustrated Lewis Pairs with Chloro-Diazirines: Cleavage of N=N Double Bonds.

Review 4. Boron: Its Role in Energy-Related Processes and Applications.

5. Triarylborane-Catalyzed Alkenylation Reactions of Aryl Esters with Diazo Compounds.

6. Understanding the Influence of Donor-Acceptor Diazo Compounds on the Catalyst Efficiency of B(C6 F5 )3 Towards Carbene Formation.

1. Ta₂ ⁺-mediated ammonia synthesis from N₂ and H₂ at ambient temperature.

2. B(C₆F₅)₃-catalyzed dehydrogenative cyclization of N-tosylhydrazones and anilines via a Lewis adduct: a combined experimental and computational investigation.

6. Understanding the Influence of Donor-Acceptor Diazo Compounds on the Catalyst Efficiency of B(C₆ F₅ )₃ Towards Carbene Formation.