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Literature DB >> 29206473

Carbonyl Iron Powder: A Reagent for Nitro Group Reductions under Aqueous Micellar Catalysis Conditions.

Nicholas R Lee¹, Agata A Bikovtseva¹, Margery Cortes-Clerget¹, Fabrice Gallou², Bruce H Lipshutz¹.

Abstract

An especially mild, safe, efficient, and environmentally responsible reduction of aromatic and heteroaromatic nitro-group-containing educts is reported that utilizes very inexpensive carbonyl iron powder (CIP), a highly active commercial grade of iron powder. These reductions are conducted in the presence of nanomicelles composed of TPGS-750-M in water, a recyclable aqueous micellar reaction medium. This new technology also shows broad scope and scalability and presents opportunities for multistep one-pot sequences involving this reducing agent.

Entities: Chemical Disease

Year: 2017 PMID： 29206473 DOI： 10.1021/acs.orglett.7b03216

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

4 in total

1. CO-free, aqueous mediated, instant and selective reduction of nitrobenzene via robustly stable chalcogen stabilised iron carbonyl clusters (Fe₃E₂(CO)₉, E = S, Se, Te).

Authors: Charu Sharma; Avinash Kumar Srivastava; Aditi Soni; Sangeeta Kumari; Raj Kumar Joshi
Journal: RSC Adv Date: 2020-09-01 Impact factor: 4.036

Carbonyl Iron Powder: A Reagent for Nitro Group Reductions under Aqueous Micellar Catalysis Conditions.

1. CO-free, aqueous mediated, instant and selective reduction of nitrobenzene via robustly stable chalcogen stabilised iron carbonyl clusters (Fe₃E₂(CO)₉, E = S, Se, Te).

2. Constructing new metal-organic frameworks with complicated ligands from "One-Pot" in situ reactions.

3. A new, substituted palladacycle for ppm level Pd-catalyzed Suzuki-Miyaura cross couplings in water.

4. Sustainable ppm level palladium-catalyzed aminations in nanoreactors under mild, aqueous conditions.

Carbonyl Iron Powder: A Reagent for Nitro Group Reductions under Aqueous Micellar Catalysis Conditions.

1. CO-free, aqueous mediated, instant and selective reduction of nitrobenzene via robustly stable chalcogen stabilised iron carbonyl clusters (Fe3E2(CO)9, E = S, Se, Te).

2. Constructing new metal-organic frameworks with complicated ligands from "One-Pot" in situ reactions.

3. A new, substituted palladacycle for ppm level Pd-catalyzed Suzuki-Miyaura cross couplings in water.

4. Sustainable ppm level palladium-catalyzed aminations in nanoreactors under mild, aqueous conditions.

1. CO-free, aqueous mediated, instant and selective reduction of nitrobenzene via robustly stable chalcogen stabilised iron carbonyl clusters (Fe₃E₂(CO)₉, E = S, Se, Te).