Literature DB >> 29205746

Well-Defined Chiral Gold(III) Complexes: New Opportunities in Asymmetric Catalysis.

Jessica Rodriguez1, Didier Bourissou1.   

Abstract

Square way to heaven: As a result of their square-planar geometry, the reactive site of gold(III) complexes is much closer to the ancillary ligands. This offers new perspectives in asymmetric catalysis, as recently evidenced by the groups of Wong and Toste with well-defined chiral complexes.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  BINOL; N-heterocyclic carbenes (NHCs); asymmetric catalysis; cyclometalated complexes; gold

Year:  2017        PMID： 29205746     DOI： 10.1002/anie.201710105

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Optical resolution of 1,16-dihydroxytetraphenylene by chiral gold(iii) complexation and its applications as chiral ligands in asymmetric catalysis.

Authors:  Jia Guo; Wen-Bin Xiong; Hao-Ran Ma; Luoyi Fan; You-Yun Zhou; Henry N C Wong; Jian-Fang Cui
Journal:  Chem Sci       Date:  2022-03-24       Impact factor: 9.969

2.  Homogeneous Gold Redox Chemistry: Organometallics, Catalysis, and Beyond.

Authors:  Banruo Huang; Mingyou Hu; F Dean Toste
Journal:  Trends Chem       Date:  2020-06-02

3.  Versatility and adaptative behaviour of the P^N chelating ligand MeDalphos within gold(i) π complexes.

Authors:  Miquel Navarro; Alberto Toledo; Sonia Mallet-Ladeira; E Daiann Sosa Carrizo; Karinne Miqueu; Didier Bourissou
Journal:  Chem Sci       Date:  2020-02-04       Impact factor: 9.825

4.  Catalytic Activity of trans-Bis(pyridine)gold Complexes.

Authors:  Ann Christin Reiersølmoen; Dániel Csókás; Sigurd Øien-Ødegaard; Alan Vanderkooy; Arvind Kumar Gupta; Anna-Carin C Carlsson; Andreas Orthaber; Anne Fiksdahl; Imre Pápai; Máté Erdélyi
Journal:  J Am Chem Soc       Date:  2020-03-23       Impact factor: 15.419

Review 5.  New-Generation Ligand Design for the Gold-Catalyzed Asymmetric Activation of Alkynes.

Authors:  Giuseppe Zuccarello; Imma Escofet; Ulysse Caniparoli; Antonio M Echavarren
Journal:  Chempluschem       Date:  2021-09       Impact factor: 2.863
  5 in total

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