Literature DB >> 29175949

Efficient utilization of renewable feedstocks: the role of catalysis and process design.

Regina Palkovits1, Irina Delidovich2.   

Abstract

Renewable carbon feedstocks such as biomass and CO2 present an important element of future circular economy. Especially biomass as highly functionalized feedstock provides manifold opportunities for the transformation into attractive platform chemicals. However, this change of the resources requires a paradigm shift in refinery design. Fossil feedstocks are processed in gas phase at elevated temperature. In contrast, biorefineries are based on processes in polar solvents at moderate conditions to selectively deoxygenate the polar, often thermally instable and high-boiling molecules. Here, challenges of catalytic deoxygenation, novel strategies for separation and opportunities provided at the interface to biotechnology are discussed in form of showcases.This article is part of a discussion meeting issue 'Providing sustainable catalytic solutions for a rapidly changing world'.
© 2017 The Author(s).

Entities:  

Keywords:  biomass; catalysis; deoxygenation; separation

Year:  2018        PMID: 29175949      PMCID: PMC5719221          DOI: 10.1098/rsta.2017.0064

Source DB:  PubMed          Journal:  Philos Trans A Math Phys Eng Sci        ISSN: 1364-503X            Impact factor:   4.226


  34 in total

1.  Catalytic conversion of cellulose into sugar alcohols.

Authors:  Atsushi Fukuoka; Paresh L Dhepe
Journal:  Angew Chem Int Ed Engl       Date:  2006-08-04       Impact factor: 15.336

2.  Cellulose conversion into polyols catalyzed by reversibly formed acids and supported ruthenium clusters in hot water.

Authors:  Chen Luo; Shuai Wang; Haichao Liu
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

3.  Direct catalytic conversion of cellulose into ethylene glycol using nickel-promoted tungsten carbide catalysts.

Authors:  Na Ji; Tao Zhang; Mingyuan Zheng; Aiqin Wang; Hui Wang; Xiaodong Wang; Jingguang G Chen
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

4.  Production of high-quality diesel from biomass waste products.

Authors:  Avelino Corma; Olalla de la Torre; Michael Renz; Nicolas Villandier
Journal:  Angew Chem Int Ed Engl       Date:  2011-01-31       Impact factor: 15.336

Review 5.  Itaconic acid--a biotechnological process in change.

Authors:  Tobias Klement; Jochen Büchs
Journal:  Bioresour Technol       Date:  2012-12-08       Impact factor: 9.642

6.  Direct synthesis of 1,6-hexanediol from HMF over a heterogeneous Pd/ZrP catalyst using formic acid as hydrogen source.

Authors:  Jaya Tuteja; Hemant Choudhary; Shun Nishimura; Kohki Ebitani
Journal:  ChemSusChem       Date:  2013-11-20       Impact factor: 8.928

Review 7.  Catalytic total hydrodeoxygenation of biomass-derived polyfunctionalized substrates to alkanes.

Authors:  Yoshinao Nakagawa; Sibao Liu; Masazumi Tamura; Keiichi Tomishige
Journal:  ChemSusChem       Date:  2015-02-25       Impact factor: 8.928

8.  Synergy between the metal nanoparticles and the support for the hydrogenation of functionalized carboxylic acids to diols on Ru/TiO2.

Authors:  Ana Primo; Patricia Concepción; Avelino Corma
Journal:  Chem Commun (Camb)       Date:  2011-02-10       Impact factor: 6.222

Review 9.  One-pot conversion of cellulose to ethylene glycol with multifunctional tungsten-based catalysts.

Authors:  Aiqin Wang; Tao Zhang
Journal:  Acc Chem Res       Date:  2013-02-19       Impact factor: 22.384

10.  Liquid alkanes with targeted molecular weights from biomass-derived carbohydrates.

Authors:  Ryan M West; Zhen Y Liu; Maximilian Peter; James A Dumesic
Journal:  ChemSusChem       Date:  2008       Impact factor: 8.928

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  3 in total

1.  Providing sustainable catalytic solutions for a rapidly changing world.

Authors:  Graham J Hutchings; C Richard Catlow; Nicholas J Turner
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2018-01-13       Impact factor: 4.226

2.  Conformational Flexibility as a Tool for Enabling Site-Selective Functionalization of Unactivated sp3 C-O Bonds in Cyclic Acetals.

Authors:  Ciro Romano; Laura Talavera; Enrique Gómez-Bengoa; Ruben Martin
Journal:  J Am Chem Soc       Date:  2022-06-24       Impact factor: 16.383

3.  Functional Phenylboronate Polymers for the Recovery of Diols, Sugar Alcohols, and Saccharides from Aqueous Solution.

Authors:  Guido Schroer; Valérie Toussaint; Stephanie Bachmann; Ann-Christin Pöppler; Christian Henning Gierlich; Irina Delidovich
Journal:  ChemSusChem       Date:  2021-05-05       Impact factor: 9.140

  3 in total

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