Literature DB >> 29155462

Iron(II)-Catalyzed Direct Synthesis of NH Sulfoximines from Sulfoxides.

Hao Yu1, Zhen Li1, Carsten Bolm1.   

Abstract

Free NH-sulfoximines were directly prepared from sulfoxides through iron catalysis by applying a readily available, shelf-stable hydroxylamine triflic acid salt. No additional oxidant is needed, and the substrate scope is broad, including a range of heterocyclic compounds.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  heterocycles; imidation; iron; sulfoxides; sulfoximines

Year:  2017        PMID： 29155462     DOI： 10.1002/anie.201710498

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

1.  SuFEx Chemistry of Thionyl Tetrafluoride (SOF4 ) with Organolithium Nucleophiles: Synthesis of Sulfonimidoyl Fluorides, Sulfoximines, Sulfonimidamides, and Sulfonimidates.

Authors:  Bing Gao; Suhua Li; Peng Wu; John E Moses; K Barry Sharpless
Journal:  Angew Chem Int Ed Engl       Date:  2018-01-16       Impact factor: 15.336

Review 2.  Synthesis and Transformations of NH-Sulfoximines.

Authors:  Michael Andresini; Arianna Tota; Leonardo Degennaro; James A Bull; Renzo Luisi
Journal:  Chemistry       Date:  2021-10-13       Impact factor: 5.020

3.  One-Pot Synthesis of N-Iodo Sulfoximines from Sulfides.

Authors:  Anže Zupanc; Marjan Jereb
Journal:  J Org Chem       Date:  2021-03-25       Impact factor: 4.354

4.  Modular Sulfondiimine Synthesis Using a Stable Sulfinylamine Reagent.

Authors:  Ze-Xin Zhang; Thomas Q Davies; Michael C Willis
Journal:  J Am Chem Soc       Date:  2019-08-09       Impact factor: 15.419

5.  Modern Stereoselective Synthesis of Chiral Sulfinyl Compounds.

Authors:  Elżbieta Wojaczyńska; Jacek Wojaczyński
Journal:  Chem Rev       Date:  2020-04-29       Impact factor: 60.622

6.  Iron-Catalyzed Intramolecular Arene C(sp2 )-H Amidations under Mechanochemical Conditions.

Authors:  Peng Shi; Yongliang Tu; Deshen Kong; Peng Wu; Ding Ma; Carsten Bolm
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-10       Impact factor: 16.823

7.  Sulfoximines-Assisted Rh(III)-Catalyzed C-H Activation and Intramolecular Annulation for the Synthesis of Fused Isochromeno-1,2-Benzothiazines Scaffolds under Room Temperature.

Authors:  Bao Wang; Xu Han; Jian Li; Chunpu Li; Hong Liu
Journal:  Molecules       Date:  2020-05-28       Impact factor: 4.411

8.  Harnessing Sulfinyl Nitrenes: A Unified One-Pot Synthesis of Sulfoximines and Sulfonimidamides.

Authors:  Thomas Q Davies; Michael J Tilby; Jack Ren; Nicholas A Parker; David Skolc; Adrian Hall; Fernanda Duarte; Michael C Willis
Journal:  J Am Chem Soc       Date:  2020-08-25       Impact factor: 15.419

9.  A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N-O Reagent as the "Amino" Source and "Oxidant".

Authors:  Sayanti Chatterjee; Ingolf Harden; Giovanni Bistoni; Rebeca G Castillo; Sonia Chabbra; Maurice van Gastel; Alexander Schnegg; Eckhard Bill; James A Birrell; Bill Morandi; Frank Neese; Serena DeBeer
Journal:  J Am Chem Soc       Date:  2022-02-04       Impact factor: 15.419

10.  Hydroxylamine-Derived Reagent as a Dual Oxidant and Amino Group Donor for the Iron-Catalyzed Preparation of Unprotected Sulfinamides from Thiols.

Authors:  Sayanti Chatterjee; Szabolcs Makai; Bill Morandi
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-10       Impact factor: 16.823
  10 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.