Literature DB >> 29152970

Pd-Catalyzed Enantio- and Regioselective Formation of Allylic Aryl Ethers.

Jianing Xie1, Wusheng Guo1, Aijie Cai1, Eduardo C Escudero-Adán1, Arjan W Kleij1,2.   

Abstract

A general methodology for the synthesis of enantioenriched tertiary allylic aryl ethers through Pd-catalyzed decarboxylative reactions of vinyl cyclic carbonates and phenols is presented. Switching of the regioselectivity toward the formation of linear products by a judicious choice of the ligand is also reported.

Entities:  

Year:  2017        PMID: 29152970     DOI: 10.1021/acs.orglett.7b03247

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Synergistic Peptide and Gold Catalysis: Enantioselective Addition of Branched Aldehydes to Allenamides.

Authors:  Leo D M Nicholls; Helma Wennemers
Journal:  Chemistry       Date:  2021-10-13       Impact factor: 5.020

2.  Palladium-catalyzed allylic etherification of phenols with vinyl ethylene carbonate.

Authors:  Shibo Lin; Xiaotian Zhao; Lihui He; Xuanhao Li; Qian Jiang; Lan Xiang; Yongqin Ye; Xiaohong Gan
Journal:  Front Chem       Date:  2022-07-22       Impact factor: 5.545

3.  Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications.

Authors:  Muhammad Salman; Yaoyao Xu; Shahid Khan; Junjie Zhang; Ajmal Khan
Journal:  Chem Sci       Date:  2020-05-06       Impact factor: 9.825

  3 in total

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