Literature DB >> 29151607

Zeeman effect in sulfur monoxide: A tool to probe magnetic fields in star forming regions.

Gabriele Cazzoli1, Valerio Lattanzi1,2, Sonia Coriani3, Jürgen Gauss4, Claudio Codella5, Andrés Asensio Ramos6, José Cernicharo7, Cristina Puzzarini1,5.   

Abstract

CONTEXT: Magnetic fields play a fundamental role in star formation processes and the best method to evaluate their intensity is to measure the Zeeman effect of atomic and molecular lines. However, a direct measurement of the Zeeman spectral pattern from interstellar molecular species is challenging due to the high sensitivity and high spectral resolution required. So far, the Zeeman effect has been detected unambiguously in star forming regions for very few non-masing species, such as OH and CN. AIMS: We decided to investigate the suitability of sulfur monoxide (SO), which is one of the most abundant species in star forming regions, for probing the intensity of magnetic fields via the Zeeman effect.
METHODS: We investigated the Zeeman effect for several rotational transitions of SO in the (sub-)mm spectral regions by using a frequency-modulated, computer-controlled spectrometer, and by applying a magnetic field parallel to the radiation propagation (i.e., perpendicular to the oscillating magnetic field of the radiation). To support the experimental determination of the g factors of SO, a systematic quantum-chemical investigation of these parameters for both SO and O2 has been carried out.
RESULTS: An effective experimental-computational strategy for providing accurate g factors as well as for identifying the rotational transitions showing the strongest Zeeman effect has been presented. Revised g factors have been obtained from a large number of SO rotational transitions between 86 and 389 GHz. In particular, the rotational transitions showing the largest Zeeman shifts are: N, J = 2, 2 ← 1, 1 (86.1 GHz), N, J = 4, 3 ← 3, 2 (159.0 GHz), N, J = 1, 1 ← 0, 1 (286.3 GHz), N, J = 2, 2 ← 1, 2 (309.5 GHz), and N, J = 2, 1 ← 1, 0 (329.4 GHz). Our investigation supports SO as a good candidate for probing magnetic fields in high-density star forming regions.

Entities:  

Keywords:  ISM: molecules; magnetic fields; methods: data analysis; methods: laboratory: molecular; molecular data

Year:  2017        PMID: 29151607      PMCID: PMC5693346          DOI: 10.1051/0004-6361/201730858

Source DB:  PubMed          Journal:  Astron Astrophys        ISSN: 0004-6361            Impact factor:   5.802


  12 in total

1.  Spin-orbit couplings within the equation-of-motion coupled-cluster framework: Theory, implementation, and benchmark calculations.

Authors:  Evgeny Epifanovsky; Kerstin Klein; Stella Stopkowicz; Jürgen Gauss; Anna I Krylov
Journal:  J Chem Phys       Date:  2015-08-14       Impact factor: 3.488

2.  Basis-set extrapolation techniques for the accurate calculation of molecular equilibrium geometries using coupled-cluster theory.

Authors:  Miriam Heckert; Mihály Kállay; David P Tew; Wim Klopper; Jürgen Gauss
Journal:  J Chem Phys       Date:  2006-07-28       Impact factor: 3.488

Review 3.  Chemical evolution of star-forming regions.

Authors:  E F van Dishoeck; G A Blake
Journal:  Annu Rev Astron Astrophys       Date:  1998       Impact factor: 30.065

4.  Gauge-origin independent calculation of magnetizabilities and rotational g tensors at the coupled-cluster level.

Authors:  Jürgen Gauss; Kenneth Ruud; Mihály Kállay
Journal:  J Chem Phys       Date:  2007-08-21       Impact factor: 3.488

5.  Calculation of electronic g-tensors using coupled cluster theory.

Authors:  Jürgen Gauss; Mihály Kállay; Frank Neese
Journal:  J Phys Chem A       Date:  2009-10-29       Impact factor: 2.781

6.  The rotational spectra of HD17O and D2(17)O: experiment and quantum-chemical calculations.

Authors:  Cristina Puzzarini; Gabriele Cazzoli; Jürgen Gauss
Journal:  J Chem Phys       Date:  2012-10-21       Impact factor: 3.488

7.  High resolution spectral analysis of oxygen. I. Isotopically invariant Dunham fit for the X(3)Σ(g)(-), a(1)Δ(g), b(1)Σ(g)(+) states.

Authors:  Shanshan Yu; Charles E Miller; Brian J Drouin; Holger S P Müller
Journal:  J Chem Phys       Date:  2012-07-14       Impact factor: 3.488

8.  Sub-Doppler resolution in the THz frequency domain: 1 kHz accuracy at 1 THz by exploiting the Lamb-dip technique.

Authors:  Gabriele Cazzoli; Cristina Puzzarini
Journal:  J Phys Chem A       Date:  2013-10-04       Impact factor: 2.781

9.  Change in the chemical composition of infalling gas forming a disk around a protostar.

Authors:  Nami Sakai; Takeshi Sakai; Tomoya Hirota; Yoshimasa Watanabe; Cecilia Ceccarelli; Claudine Kahane; Sandrine Bottinelli; Emmanuel Caux; Karine Demyk; Charlotte Vastel; Audrey Coutens; Vianney Taquet; Nagayoshi Ohashi; Shigehisa Takakuwa; Hsi-Wei Yen; Yuri Aikawa; Satoshi Yamamoto
Journal:  Nature       Date:  2014-02-12       Impact factor: 49.962

10.  Vibrational Energy Levels via Finite-Basis Calculations Using a Quasi-Analytic Form of the Kinetic Energy.

Authors:  Juana Vázquez; Michael E Harding; John F Stanton; Jürgen Gauss
Journal:  J Chem Theory Comput       Date:  2011-04-22       Impact factor: 6.006

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