Stability of heavy metals in soil washing residue with and without biochar addition under accelerated ageing.

Soil washing residue (SWR), which typically concentrates the washed toxic metals and is comprised of high contents of clay particles, may pose risks to the surrounding environment. This study aims to simulate accelerated ageing to assess the stability of selected metals (Cd2+ (132mg/kg), Cu2+ (248mg/kg) and Pb2+ (3470mg/kg)) in a SWR (89.68% of clay) with and without biochar treatment. The soil was incubated under constant moisture and wet-dry cycles (accelerated ageing), respectively, and the mobility and fractions of heavy metals in the soils with and without biochar treatment were examined. Under the constant moisture condition, biochar addition at 5% w/w reduced the leached Cd2+ (by 1.81%) and Cu2+ (by 8.70%) from SWR at day 1 and the leached Cu2+ (by 51.08%) and Pb2+ (by 25.36%) from SWR at day 14; however, the leached metals in the TCLP solution from the biochar-amended soils still exceed the regulatory limits (1mg/L for Cd2+, 5mg/L for Pb2+, no regulatory limits for Cu2+). Conversely, accelerated ageing (14days) significantly increased the fractions of exchangeable Cd2+ (from 3.63-3.94% to 6.21-6.29%) and Pb2+ (from 0.025-0.027% to 0.034-0.041%) as well as the TCLP leachabilities of Cd2+ (from 2.91-3.28% to 3.46-3.73%), Cu2+ (from 0.08-0.10% to 0.03-0.06%) and Pb2+ (from 0.25-0.35% to 0.52-0.57%) in the soils, as compared with those incubated under constant moisture, regardless of biochar addition. This study reveals challenges associated with stabilising SWR due to the presence of residual fine-grained particles.