Literature DB >> 29142328

Discovery of methyl silane and confirmation of silyl cyanide in IRC +10216.

J Cernicharo1, M Agúndez1, L Velilla Prieto1, M Guélin2, J R Pardo1, C Kahane3, C Marka4, C Kramer4, S Navarro4, G Quintana-Lacaci1, J P Fonfría1, N Marcelino1, B Tercero1, E Moreno1, S Massalkhi1, M Santander-García1, M C McCarthy5, C A Gottlieb5, J L Alonso6.   

Abstract

We report the discovery in space of methyl silane, CH3SiH3, from observations of ten rotational transitions between 80 and 350 GHz (Ju from 4 to 16) with the IRAM 30 m radio telescope. The molecule was observed in the envelope of the C-star IRC +10216. The observed profiles and our models for the expected emission of methyl silane suggest that the it is formed in the inner zones of the circumstellar envelope, 1-40 R*, with an abundance of (0.5-1) × 10-8 relative to H2. We also observed several rotational transitions of silyl cyanide (SiH3CN), confirming its presence in IRC +10216 in particular, and in space in general. Our models indicate that silyl cyanide is also formed in the inner regions of the envelope, around 20 R*, with an abundance relative to H2 of 6×10-10. The possible formation mechanisms of both species are discussed. We also searched for related chemical species but only upper limits could be obtained.

Entities:  

Keywords:  astrochemistry; stars: AGB and post-AGB; stars: carbon; stars: individual: IRC+10216

Year:  2017        PMID: 29142328      PMCID: PMC5683346          DOI: 10.1051/0004-6361/201731672

Source DB:  PubMed          Journal:  Astron Astrophys        ISSN: 0004-6361            Impact factor:   5.802


  5 in total

1.  Detection of the silyl radical SiH3 by infrared diode-laser spectroscopy.

Authors: 
Journal:  Phys Rev Lett       Date:  1986-03-03       Impact factor: 9.161

2.  Dynamics of the reaction C(3P)+SiH4: experiments and calculations.

Authors:  I-Chung Lu; Wei-Kan Chen; Wen-Jian Huang; Shih-Huang Lee
Journal:  J Chem Phys       Date:  2008-10-28       Impact factor: 3.488

3.  SI-BEARING MOLECULES TOWARD IRC+10216: ALMA UNVEILS THE MOLECULAR ENVELOPE OF CWLEO.

Authors:  L Velilla Prieto; J Cernicharo; G Quintana-Lacaci; M Agúndez; A Castro-Carrizo; J P Fonfŕia; N Marcelino; J Zúñiga; A Requena; A Bastida; F Lique; M Guélin
Journal:  Astrophys J Lett       Date:  2015-06-01       Impact factor: 7.413

4.  Discovery of SiCSi in IRC +10216: A missing link between gas and dust carriers of Si-C bonds.

Authors:  J Cernicharo; M C McCarthy; C A Gottlieb; M Agúndez; L Velilla Prieto; J H Baraban; P B Changala; M Guélin; C Kahane; M A Martin-Drumel; N A Patel; N J Reilly; J F Stanton; G Quintana-Lacaci; S Thorwirth; K H Young
Journal:  Astrophys J Lett       Date:  2015-06-10       Impact factor: 7.413

5.  The abundance of 28Si32S, 29Si32S, 28Si34S, and 30Si32S in the inner layers of the envelope of IRC+10216.

Authors:  J P Fonfría; J Cernicharo; M J Richter; M Fernández-López; L Velilla Prieto; J H Lacy
Journal:  Mon Not R Astron Soc       Date:  2015-08-13       Impact factor: 5.287

  5 in total
  2 in total

1.  The Chemistry of Cosmic Dust Analogues from C, C2, and C2H2 in C-Rich Circumstellar Envelopes.

Authors:  Gonzalo Santoro; Lidia Martínez; Koen Lauwaet; Mario Accolla; Guillermo Tajuelo-Castilla; Pablo Merino; Jesús M Sobrado; Ramón J Peláez; Víctor J Herrero; Isabel Tanarro; Á Lvaro Mayoral; Marcelino Agúndez; Hassan Sabbah; Christine Joblin; José Cernicharo; José Ángel Martín-Gago
Journal:  Astrophys J       Date:  2020-06-02       Impact factor: 5.874

2.  On the Potential of Silicon as a Building Block for Life.

Authors:  Janusz Jurand Petkowski; William Bains; Sara Seager
Journal:  Life (Basel)       Date:  2020-06-10
  2 in total

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