| Literature DB >> 29115311 |
Xi Kang1, Lin Xiong, Shuxin Wang, Yong Pei, Manzhou Zhu.
Abstract
Considering the significant effect of the size of a nanocluster on its optical energy gap, we herein exploit the concept of de-assembly to render a blue-shift of the photoluminescent emission as well as an enhancement of the quantum yield (QY) of assembled M25 nanoclusters. The de-assembly splits an assembled M13-dimer Pt2Ag23(PPh)10Cl7 into a sole-M13-kernel Pt1Ag12(dppm)5(SPhMe2)2, via a Pt1Ag24(SPhMe2)18 nanocluster.Year: 2017 PMID： 29115311 DOI： 10.1039/c7cc05996e
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222