Literature DB >> 29114933

Di(1-naphthyl) methanol ester of carboxylic acids for absolute stereochemical determination.

Jun Zhang1, Wei Sheng1, Hadi Gholami1, Tatsuo Nehira2, Babak Borhan1.   

Abstract

The absolute stereochemistry of chiral carboxylic acids is determined as a di(1-naphthyl)methanol ester derivative. Computational scoring of conformations favoring either P or M helicity of the naphthyl groups, capable of exciton-coupled circular dichroic coupling, leads to a predicted stereochemistry for the derivatized carboxylic acids.
© 2017 Wiley Periodicals, Inc.

Entities:  

Keywords:  ECCD; absolute stereochemistry; carboxylic acids; chiral sensing; chirality; computational analysis

Year:  2017        PMID： 29114933     DOI： 10.1002/chir.22775

Source DB:  PubMed          Journal:  Chirality        ISSN： 0899-0042            Impact factor:   2.437


  2 in total

1.  Diasteroselective multi-component assemblies from dynamic covalent imine condensation and metal-coordination chemistry: mechanism and narcissistic stereochemistry self-sorting.

Authors:  Elena Badetti; Nadia Alessandra Carmo Dos Santos; Francesca A Scaramuzzo; Carlo Bravin; Klaus Wurst; Giulia Licini; Cristiano Zonta
Journal:  RSC Adv       Date:  2018-05-29       Impact factor: 4.036

2.  Optical Activity and Helicity Enhancement of Highly Sensitive Dinaphthylmethane-Based Stereodynamic Probes for Secondary Alcohols.

Authors:  Tomasz Mądry; Agnieszka Czapik; Marcin Kwit
Journal:  ACS Omega       Date:  2019-02-14
  2 in total

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