| Literature DB >> 29093299 |
Shinobu Takizawa1, Makoto Sako1, Kenta Kishi1, Masashi Shigenobu1, Giang Vo-Thanh2, Hiroaki Sasai1.
Abstract
An enantioselective intermolecular Rauhut-Currier (RC) reaction of nitroalkenes with ethyl allenoate has been established with quinidine-derived β-isocupreidine. The present RC reaction afforded α-functionalized allenoates 3 in up to 94% yield with 59% enantiomeric excess (ee).Entities:
Keywords: Rauhut–Currier reaction; chiral organocatalysis; nitroalkene; α-functionalized allenoate
Mesh：
Substances：
Year: 2017 PMID： 29093299 DOI： 10.1248/cpb.c17-00554
Source DB: PubMed Journal: Chem Pharm Bull (Tokyo) ISSN： 0009-2363 Impact factor: 1.645